Synthesis of Sumanene

C21H12
Principal investigator | Hidehiro Sakurai |
---|---|
Publication year | 2003 |
Synthesis type | Total |
Number of steps | 4 (linear) |
References |
Part 1 of 1

- KOt-Bu , n-BuLi
- Br(CH2)2Br
- n-Bu3SnCl
THF
-78 °C to RT, 17 h, 74%


NMP
-78 °C to RT, 13 h, 16%
"Also isolated was the syn:anti diastereoisomer (47 % yield)."


DDQ
PhMe
Reflux, 3 h, 70%
