Synthesis of Hirsutene

Structure of Hirsutene

C15H24

Principal investigatorAndrew E. Greene
Publication year1980
Synthesis typeFormal
Number of steps 10 (linear)
References
Part 1 of 1
intermediate structure + intermediate structure
Et3N
intermediate structure
CH2N2
intermediate structure
NaBH4
100%
intermediate structure
Cr(ClO4)2
50-60%
intermediate structure + intermediate structure
POCl3, Zn-Cu
Et2O
60%
intermediate structure
CH2N2
intermediate structure
NaBH4
intermediate structure
Cr(ClO4)2
intermediate structure
HCO2H, HClO4
H2O
intermediate structure
Remaining...
70% (1 step)
"See: <i>Tetrahedron Lett. 1976, 17, 195."
intermediate structure