Sample reactions
intermediate structure
(Me3Sn)2, LiCl, Pd(PPh3)4
THF
60 °C, , 80%
intermediate structure
intermediate structure intermediate structure
CO, LiCl, Pd2(dba)3, Ph3As
NMP
70 °C, , 80%
intermediate structure
intermediate structure
CuCl, Pd(PPh3)4, CuCl2
DMSO
60 °C, 2 h, 82%
intermediate structure
intermediate structure
LiCl, Pd(PPh3)4
THF
RT, 7 d
intermediate structure
intermediate structure
n-Bu3SnH, Pd(PPh3)4
THF
RT, 60 min, 86%
intermediate structure
intermediate structure
Pd(PPh3)4, VinylSnBu3
Dioxane
100 °C, 16 h, 91%
intermediate structure
intermediate structure intermediate structure
CuCl, LiCl, Pd(PPh3)4
DMSO
RT, 10 min, 53% (3 steps)
intermediate structure
intermediate structure intermediate structure
CuCl, LiCl, Pd(PPh3)4
DMSO
60 °C, 60 min, 61% (3 steps)
intermediate structure
intermediate structure
n-Bu3SnH, Pd(PPh3)4
PhMe
RT, 20 min, 88%
intermediate structure
intermediate structure intermediate structure
i-Pr2NEt, Pd2(dba)3
NMP
RT, 22 h, 62%
intermediate structure
intermediate structure
Pd(PPh3)4, (n-Bu3Sn)2
PhMe
110 °C, 24 h, 70%
intermediate structure
intermediate structure intermediate structure
CuI, Pd2(dba)3.CHCl3, Ph3As
DMF
RT, 48 h, 100%
intermediate structure
intermediate structure intermediate structure
PdCl2.2MeCN
DMF
RT, ON, 68%
intermediate structure
intermediate structure intermediate structure
Pd(PPh3)2Cl2
DMF
90 °C, 5 h, 74%
intermediate structure