Sample reactions
intermediate structure
(PhO)2P(O)N3, DEAD, Ph3P
THF
0 °C, 24 h, 95%
intermediate structure
intermediate structure
DIAD, Ph3P, Zn(N3)2.2Pyr
THF
RT, 38 h, 30%
intermediate structure
intermediate structure
DEAD, Ph3P, Zn(N3)2.2Pyr
RT, 12 h, 100%
intermediate structure
intermediate structure
DEAD, Ph3P, TsNHBoc
THF
0 °C to RT, 24 h, 88%
intermediate structure
intermediate structure
DIAD, Ph3P
THF
91%
intermediate structure
intermediate structure
(PhO)2P(O)N3, DEAD, Ph3P
THF
0 °C to RT, 40 min, 82%
intermediate structure
intermediate structure
DIAD, Ph3P
THF
RT to Reflux, 3 h
intermediate structure
intermediate structure intermediate structure
DIAD, Ph3P
THF
0 °C to RT, 2.5 h, 94%
intermediate structure
intermediate structure
DIAD, Ph3P
Et2O
-20 °C, 5 h
intermediate structure
intermediate structure intermediate structure
n-Bu3P, DEAD
THF
0 °C, 4 h, 83%
intermediate structure
intermediate structure
n-Bu3P, PhSO2NHMe
81%
intermediate structure
intermediate structure
DEAD, Ph3P, 4-Methoxyphenol
CH2Cl2
0 °C to RT, 3 d, 95%
intermediate structure
intermediate structure intermediate structure
DEAD, Ph3P
PhH
5 °C to RT, 15 min, 90%
intermediate structure
intermediate structure intermediate structure
DEAD, Ph3P
PhH
5 °C to RT, 15 min, 100%
intermediate structure
intermediate structure
DEAD, Ph3P, ZnBr2
THF
RT, , 91%
intermediate structure
intermediate structure
DEAD, Ph3P, BzOH
Et2O
-25 °C, 60 min
intermediate structure
intermediate structure
DEAD, H2O, LiOH, Ph3P, p-NO2BzOH
THF
-20 °C, 3 h, 80%
intermediate structure
intermediate structure
DEAD, Ph3P
THF
-20 °C, 75 min, 66%
intermediate structure
intermediate structure
DEAD, Ph3P, NsNH2
PhMe
RT, 5 min, 95%
intermediate structure
intermediate structure
(PhO)2P(O)N3, DEAD, Ph3P
THF
50%
intermediate structure
intermediate structure
(PhO)2P(O)N3, DEAD, Ph3P
THF
0 °C, , 88%
intermediate structure
intermediate structure
DEAD, Phthalimide, Ph2PMe
THF
0 °C to RT, 60 min, 50%
intermediate structure
intermediate structure intermediate structure
DIAD, Ph3P
78%
intermediate structure
intermediate structure intermediate structure
DIAD, Ph3P
THF
80 °C, 3 h, 54%
intermediate structure
intermediate structure
DIAD, Ph3P
PhH
RT, ON, 98%
intermediate structure