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Named reactions

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Search synthesis

Alstonerine

Chemical structure of Alstonerine
C21H24N2O2
Author Stephen F. Martin
Publication year 2007
Synthesis type Total synthesis
Number of steps 15 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
Ac2O, HCl
HCO2H, H2O
RT to 55 °C, 16 h, 63%

See the Bischler-Napieralski Reaction
Chemical structure
ClCO2Bn, Et3N
CH2Cl2, MeOH
-20 °C to RT, 105 min, 76%
Chemical structure
AllylTMS, BF3.OEt2
CH2Cl2
0 °C, 60 min, 72%

See the Hosomi-Sakurai Reaction
Chemical structure
Reagent structure
i-Bu2AlH, NaOMe
PhMe, THF
-78 °C to RT, 105 min, 55%

See the Seyferth-Gilbert Homologation
Chemical structure
Co2(CO)8, DMSO
THF
65 °C, 94%

See the Pauson-Khand Reaction
Chemical structure
Boc2O, DMAP
MeCN
99%
Chemical structure
Reagent structure
i-Pr3SiH
PhMe
80 °C, 93%
Chemical structure
OsO4, NaIO4
Acetone, H2O

See the Lemieux-Johnson Oxidation
Chemical structure
NaBH4, TsOH
MeOH
55% (2 steps)
Chemical structure
i-Bu2AlH
PhMe
-78 °C
Chemical structure
MsCl, Et3N
CH2Cl2
61% (2 steps)
Chemical structure
Cl3CCOCl
Pyr
65 °C
Chemical structure
Zn
AcOH
75% (2 steps)
Chemical structure
TMSI
MeCN
78%
Chemical structure
NaH, MeI
THF
72%
Chemical structure

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