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Named reactions

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Search synthesis

Wodeshiol

Chemical structure of Wodeshiol
C20H18O8
Author Elias J. Corey
Publication year 1999
Synthesis type Total synthesis
Number of steps 8 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
VinylLi
THF
-78 °C, 30 min, 97%
Chemical structure
MnO2
CH2Cl2
0 °C, 30 min, 75%
Chemical structure
Br2, Et3N
CH2Cl2, Et2O
-78 to 0 °C, 16.5 h, 70%
Chemical structure
CBS Reagent
PhMe, CH2Cl2
-78 °C, 5.5 d, 84%

Selectivity : 94:06 er
See the Corey-Itsuno Reaction
Chemical structure
  1. t-BuLi
  2. Bu3SnCl
Et2O
-78 to -40 °C, 5 h, 84%
Chemical structure
Pd(PPh3)4, CuCl, CuCl2
DMSO
60 °C, 2 h, 82%

See the Stille Coupling
Chemical structure
VO(acac)2, t-BuOOH
CH2Cl2
0 °C, 14 h, 56%
Chemical structure
Pyr.TsOH
PhH
80 °C, 22 h, 61%
Chemical structure

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