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Named reactions

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Sumanene

Chemical structure of Sumanene
C21H12
Author Hidehiro Sakurai
Publication year 2003
Synthesis type Total synthesis
Number of steps 4 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
  1. KOt-Bu, n-BuLi
  2. Br(CH2)2Br
  3. Bu3SnCl
THF
-78 °C to RT, 17 h, 74 %
Chemical structure
Reagent structure
NMP
-78 °C to RT, 13 h, 16 %

Also isolated was the syn:anti diastereoisomer (47 % yield).
Chemical structure
Grubbs catalyst (1st gen.), C2H4
PhMe
RT, 24 h, 30 %

See the Olefin Metathesis
Chemical structure
DDQ
PhMe
Reflux, 3 h, 70 %
Chemical structure

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