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Named reactions

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Search synthesis

Aflatoxin B1

Chemical structure of Aflatoxin_B1
C17H12O6
Author Barry M. Trost
Publication year 2003
Synthesis type Total synthesis
Number of steps 9 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
HCl
EtOH
RT, 72 h, 47 %

See the Pechmann Condensation
Chemical structure
ICl
CH2Cl2
RT, 30 min, 92 %
Chemical structure
+
Chemical structure
Reagent structure
Pd2(dba)3.CHCl3, n-Bu4N+ Cl-
CH2Cl2
RT, 12 h, 89 %

See the Trost Asymmetic Allylation Alkylation
Chemical structure
PdCl2.2MeCN, HCO2H
DMF, Et3N
60 °C, 60 min, 93 %

See the Heck Coupling
Chemical structure
HCl
AcOH, H2O
RT, 48 h
Chemical structure
Sc(OTf)3, LiClO4
MeNO2
60 °C, 4 h, 32 % (2 steps)

See the Friedel-Crafts Acylation
Chemical structure
i-Bu2AlH
CH2Cl2
-78 °C, 60 min, 57 %
Chemical structure
Ac2O
AcOH
RT, 20 h
Chemical structure
PhMe
240 °C, 15 min, 24 % (2 steps)
Chemical structure

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