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Named reactions

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Centrohexaindane

The Triquinacene Route to Centrohexaindane.

Chemical structure of Centrohexaindane
C41H24
Author Dietmar Kuck
Publication year 1995
Synthesis type Total synthesis
Number of steps 6 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
TsOH
Dean-Stark
PhH
Reflux, 2 h, 90%
Chemical structure
LiAlH4
THF
Reflux, 3 h, 92%
Chemical structure
H3PO4
Dean-Stark
Xylene(s)
Reflux, 5-8 h, 33%

See the Friedel-Crafts Alkylation
Chemical structure
Br2
CCl4
Reflux, 96%

See the Wohl-Ziegler Reaction
Chemical structure
AlBr3
PhH
RT, 3 d, 40%

See the Friedel-Crafts Alkylation
Chemical structure
Pd/C
Sealed tube
500 °C, 90 min, <5%
Chemical structure

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