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Named reactions

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Centrohexaindane

The Propelane Route to Centrohexaindane.

Chemical structure of Centrohexaindane
C41H24
Author Dietmar Kuck
Publication year 1995
Synthesis type Total synthesis
Number of steps 6 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
BnBr, KF, Celite ®
MeCN
75 °C, 18 h, 89%
Chemical structure
PPA
120 °C, 12-60 h, 91%

See the Friedel-Crafts Alkylation
Chemical structure
Br2
CCl4
Reflux, 30 min, 93%

See the Wohl-Ziegler Reaction
Chemical structure
Na2HPO4, KH2PO4, NaBr
DMSO
80-100 °C, 8 h, 79%

See the Kornblum Oxidation
Chemical structure
PhLi
PhH, Et2O
40 °C, 6 h
Chemical structure
H3PO4
Soxhlet (4 Å MS)
Xylene(s)
Reflux, 25-30 h, 40% (2 steps)

See the Friedel-Crafts Alkylation
Chemical structure

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