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Named reactions

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Search synthesis

Centrohexaindane

The Fenestrane Route to Centrohexaindane.

Chemical structure of Centrohexaindane
C41H24
Author Dietmar Kuck
Publication year 1988
Synthesis type Total synthesis
Number of steps 11 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
AcOH
100 °C, 60 min, 63%

See the Michael Addition
Chemical structure
LiAlH4
THF
Reflux, 8 h, 88%
Chemical structure
H3PO4
Dean-Stark
Xylene(s)
Reflux, 2 h, 91%

See the Friedel-Crafts Alkylation
Chemical structure
CrO3, H2SO4
Acetone, H2O
RT, 12 h, 94%

See the Jones Oxidation
Chemical structure
Br2
AcOH
RT, ON, 85%
Chemical structure
KOH
THF
RT to Reflux, 17 h, 70-85%

See the Favorskii Rearrangement
Chemical structure
Cu
Quinoline
200 °C, 10 h, 33-38%
Chemical structure + Chemical structure
PhMe
120 °C, 24 h, 91%

See the Diels-Alder Reaction
Chemical structure
Na
THF, t-BuOH
Reflux, 16 h, 82%
Chemical structure
Br2
CCl4
RT, 20 min, 63%

See the Wohl-Ziegler Reaction
Chemical structure
AlBr3
PhH
40 °C to Reflux, 42 h, 80%

See the Friedel-Crafts Alkylation
Chemical structure

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