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Named reactions

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Hirsutene

Chemical structure of Hirsutene
C15H24
Author Alan C. Weedon
Publication year 1987
Synthesis type Formal synthesis
Number of steps 7 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
MeOH
RT, 5 d

See the De Mayo Reaction
Chemical structure
+
Chemical structure
TBSCl, Imidazole
DMF, CH2Cl2
0 °C to RT, 2 h, 89%

Selectivity : 50:50
Chemical structure
+
Chemical structure
TiCl3, K
THF
Reflux, 25 h, 55%

Selectivity : 69:31
See the McMurry Reaction
Chemical structure
+
Chemical structure
n-Bu4N+ F-
THF
RT, 12 h, 52%
Chemical structure
H2, PtO2
1 atm
MeOH
RT, 10 h
Chemical structure
CrO3, H2SO4
Acetone, H2O
0 °C, 47% (2 steps)

See the Jones Oxidation
Chemical structure

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70% (1 step)

Tetrahedron Lett. 1976, 17, 195.
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