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Named reactions

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Search synthesis

Hirsutene

Chemical structure of Hirsutene
C15H24
Author Dennis P. Curran
Publication year 1985
Synthesis type Total synthesis
Number of steps 12 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
  1. i-Pr2NLi
  2. TBSCl
THF, HMPA
-78 °C, 90 min
Chemical structure
CHCl3
Reflux, 5 h

See the Ireland-Claisen Rearrangement
Chemical structure
PhSeCl
CH2Cl2
-78 °C, 25 min, 75% (3 steps)
Chemical structure
H2O2
THF, H2O
0 °C, ON, 82%
Chemical structure + Chemical structure
Li.Naphthalene, CuBr.Me2S
THF, Me2S
-78 to -20 °C, 5.5 h
Chemical structure
Pyr.TsOH
EtOH
Reflux, 4 h, 75% (2 steps)
Chemical structure
i-Bu2AlH
THF
-78 °C to RT, 7 h, 83%
Chemical structure
Tf2O, Pyr
CH2Cl2
-10 °C, 70 min, 81%
Chemical structure
n-Bu4N+ I-
PhH
Reflux, 2 h, 75%

See the Finkelstein Reaction
Chemical structure
Trimethylsilylacetylene, n-BuLi
THF, HMPA
0 °C, 20 min
Chemical structure
n-Bu4N+ F-
THF
RT, 2 h, 75% (2 steps)
Chemical structure
n-Bu3SnH, AIBN
PhH
Reflux, 60 min, 64%
Chemical structure

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