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Named reactions

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Search synthesis

Hirsutene

Chemical structure of Hirsutene
C15H24
Author Philip Magnus
Publication year 1985
Synthesis type Total synthesis
Number of steps 10 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
AgBF4
CH2Cl2, DCE
-50 °C to RT, 20 h, 38%

See the Nazarov Cyclization Reaction
Chemical structure
MeLi
Et2O
-78 °C, 4 h
Chemical structure
HgCl2, HgO, H2SO4
THF, H2O
RT, 14 h, 94% (2 steps)
Chemical structure + Chemical structure
t-BuLi, CuI, BF3.OEt2
Et2O, HMPT
-120 to -20 °C, 9 h, 60%

See the Michael Addition
The yield was 74 % brsm.
Chemical structure
KF.2H2O, Et3NBn+ Cl-
MeCN
60 °C, 10 h, 84%
Chemical structure
TsCl, Et3N
CH2Cl2
RT, 94%
Chemical structure
TMS2NLi
Et2O
-78 to -30 °C, 4 h, 75%
Chemical structure
NaBH4
MeOH
0 °C, 100%
Chemical structure
  1. NaH, Imidazole
  2. CS2
  3. MeI
THF
RT to 50 °C, 92%
Chemical structure
n-Bu3SnH, AIBN
PhH
Reflux, 2 h, 70%

See the Barton-McCombie Reaction
Chemical structure

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