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Hirsutene

Chemical structure of Hirsutene
Author Paul A. Wender
Publication year 1982
Synthesis type Total synthesis
Number of steps 8 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure + Chemical structure
Mg, Ac2O, DMAP
Arrow head
Et2O
79 %

See the Grignard Reaction
Chemical structure
hν
Arrow head
Cyclohexane
Chemical structure
LiAlH4
Arrow head
Et2O
22-23 % (2 steps)
Chemical structure
Camphorsulfonic acid
Arrow head
PhH
RT, 71 %
Chemical structure
PhSH
Arrow head
100 °C, 78 %
Chemical structure
Reagent structure
H2
Arrow head
CH2Cl2


No yield reported. Several cycling were need to fully convert this product.
Chemical structure
NaIO4
Arrow head
MeOH
86 %
Chemical structure
P(OMe)3
Arrow head
PhH
170 °C, 60 %
Chemical structure

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