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Named reactions

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Search synthesis

Hirsutene

Chemical structure of Hirsutene
C15H24
Author Goverdhan Mehta
Publication year 1981
Synthesis type Total synthesis
Number of steps 10 (linear)
References

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
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Chemical structure
PhH
Reflux, 2 h, 90%

See the Diels-Alder Reaction
Chemical structure
EtOAc
30 min, 85%
Chemical structure
0.1 mmHg
500 °C, 100%
Chemical structure
BnOBz
317 °C, 12 min, 37%

The yield was 43 % brsm.
Chemical structure
H2, Pd/C
1.5 atm
EtOAc
RT, 20 min, 95%
Chemical structure
MeI, NaH
THF
10 °C to Reflux, 60 min, 65%
Chemical structure
Ph3P+CH3 Br-, NaOt-Amyl
PhMe
RT to Reflux, 3 h, 84%

See the Wittig Reaction
Chemical structure
LiAlH4
Et2O
RT, 45 min, 90%
Chemical structure
  1. NaH, Imidazole
  2. CS2
  3. MeI
THF
Reflux, 4.5 h, 88%
Chemical structure
n-Bu3SnH
PhMe
Reflux, 6 h, 19%

See the Barton-McCombie Reaction
Chemical structure

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