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Taiwaniaquinol B

Chemical structure of Taiwaniaquinol_B
C20H28O4
Author Dirk Trauner
Publication year 2006
Synthesis type Total synthesis
Number of steps 6 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
NBS
DMF
RT, 42 h, 98%
Chemical structure + Chemical structure
n-BuLi
Et2O
-25 °C to RT, 105 min, 89%
Chemical structure
Dess-Martin Periodinane
CH2Cl2, Pyr
RT, 5 min, 90%

See the Dess-Martin Oxidation
Chemical structure
TMSOTf
MeNO2
105 °C, 65 min, 70%

See the Nazarov Cyclization Reaction
Chemical structure
BCl3
CH2Cl2
0 °C, 15 min, 90%
Chemical structure
(NH4)2Ce(NO3)6, Na2S2O4
MeCN, CH2Cl2, H2O
0 °C, 4 h, 51%
Chemical structure

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