Synarchive logo
Google+ Facebook Twitter RSS Feed
Support this website
Synarchive is free but requires a lot of work. If you enjoy and find it useful, please support us by making a donation.
Named reactions

Get references and more from over 229 named organic chemical reaction

Go to the named reaction index

Protecting Groups

Get the conditions needed to install/remove a wide range of protecting groups.

Go to the protecting groups index

Search synthesis

Dodecahedrane

Chemical structure of Dodecahedrane
C20H20

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
+
Chemical structure
THF
-78 °C to RT, 23%

See the Diels-Alder Reaction
Chemical structure
KOH
MeOH, H2O
Reflux, 60 min, 98%
Chemical structure
KI3, NaHCO3
H2O
RT, 23 h, 96%
Chemical structure
NaOMe
MeOH
RT, 3 h, 96%
Chemical structure
CrO3, H2SO4
Acetone, H2O
5 °C, 2.5 h, 92%

See the Jones Oxidation
Chemical structure
Zn-Cu, NH4Cl
MeOH
RT, 5 h, 78%
Chemical structure + Chemical structure
KOH
DMSO
RT, 30 h, 77%

The product depicted is the major component of an uncharacterized mixture of isomers.
Chemical structure
H2O2, NaOH
MeOH, H2O
RT, 2.5 h, 42%

See the Baeyer-Villiger Oxidation
The product was selectively cristallized from the resulting mixture of isomers.
Chemical structure
P2O5
MsOH
50 °C, 36.5 h, 83%
Chemical structure
H2, Pd/C
3 atm
EtOAc
100 °C, 16 h, 100%
Chemical structure
NaBH3CN, HCl
MeOH, H2O
RT, 8.5 h, 85%
Chemical structure
HCl
MeOH
0 °C, 26 h, 62%
Chemical structure
  1. Li
  2. BnOCH2Cl
NH3, THF
Reflux, 60 min, 48%
Chemical structure
Et3N
PhH, t-BuOH
RT, 18 h, 90%

See the Norrish Reaction
Chemical structure
TsOH
PhH
70 °C, 8 h, 93%
Chemical structure
NH2NH2, H2O2
THF, EtOH, H2O
0 °C to RT, ON, 91%
Chemical structure
i-Bu2AlH
PhH
RT, 12 h, 97%
Chemical structure
HCrO3Cl.Pyr
CH2Cl2
RT, 90 min, 95%
Chemical structure
PhMe, MeOH
-78 °C to RT, 18 h, 36%

See the Norrish Reaction
Chemical structure
Li
NH3, THF, EtOH
Reflux, 60 min, 90%

See the Birch Reduction
Chemical structure
HCrO3Cl.Pyr
CH2Cl2
RT, 4 h, 97%
Chemical structure
KOH
THF, EtOH
RT, 5 h, 48%
Chemical structure
Et3N
PhH, t-BuOH
RT, 10 h, 100%

See the Norrish Reaction
Chemical structure
TsOH
PhH
Reflux, 75 min, 100%
Chemical structure
NH2NH2, H2O2
THF, EtOH, H2O
0 °C to RT, ON, 91%
Chemical structure
Pd/C
250 °C, 34%
Chemical structure

Report an error in this part

comments powered by Disqus
homepage - authors - molecules - named reactions - protecting groups - advanced search - contact
© 2011-2017 SynArchive