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Named reactions

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Search synthesis

Triquinacene

Chemical structure of Triquinacene
C10H10
Author Robert B. Woodward
Publication year 1964
Synthesis type Total synthesis
Number of steps 16 (linear)
Reference

Browse hundreds of other total syntheses.

Part 1 of 1
Chemical structure
CrO3.2Pyr
74%

See the Collins Oxidation
Chemical structure
AcOOH, NaOAc
AcOH, CH2Cl2
92%

See the Prilezhaev Reaction
Chemical structure
KOt-Bu
Et2O, THF
90%
Chemical structure
CrO3
Et2O, H2O
70%
Chemical structure
Pb(OAc)4
PhH
Chemical structure
MeOH
45% (2 steps)
Chemical structure
CH2N2
Chemical structure
NaOMe
MeOH

Selectivity : 70:30 S/R
Chemical structure
NaOH
MeOH, H2O
67% (3 steps)
Chemical structure
SOCl2
Chemical structure
NaN3
PhMe

See the Curtius Rearrangement
Chemical structure
MeOH
84% (3 steps)
Chemical structure
LiAlH4
THF
84%
Chemical structure
CH2O
HCO2H, H2O
94%

See the Eschweiler-Clarke Reaction
Chemical structure
H2O2
MeOH, H2O
Chemical structure
125-140 °C, 78% (2 steps)

See the Cope Elimination
Chemical structure

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