Browse by molecules
Browse by principal investigator
Browse by date
Browse by carbon count
menu
Browse Syntheses
arrow_drop_down
Named Reactions
Protecting Groups
Browse Syntheses
arrow_drop_down
Browse by molecules
Browse by principal investigator
Browse by date
Browse by carbon count
Named Reactions
Protecting Groups
Methyl carbamate
Protection :
Reagents
Solvents
Temperature
Time
Yield
DMAP
Et3N
ClCO2Me
CH2Cl2
RT
4 h
87 %
info
DMAP
,
Et3N
,
ClCO2Me
CH2Cl2
RT, 4 h, 87%
ClCO2Me
TMS2NNa
THF
-78 °C - RT
4 h
96 %
info
ClCO2Me
,
TMS2NNa
THF
-78 °C to RT, 4 h, 96%
Deprotection :
Reagents
Solvents
Temperature
Time
Yield
TMSI
CHCl3
Reflux
6 h
100 %
info
TMSI
CHCl3
Reflux, 6 h, 100%
HBr
AcOH
RT
22 h
74 %
info
HBr
AcOH
RT, 22 h, 74%