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Named reactions

Get references and more from over 225 named organic chemical reaction

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Protecting Groups

Get the conditions needed to install/remove a wide range of protecting groups.

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Search synthesis

Sharpless Epoxidation

Sharpless Epoxidation

Mechanism of the Sharpless Epoxidation

Reference

Original reference J. Am. Chem. Soc. 1980, 102, 5974.
Wikipedia link
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Sample reactions

This reaction is from the synthesis of Solandelactone E by Varinder K. Aggarwal. Show me the full synthesis.

Reactant structure
t-BuOOH, Ti(Oi-Pr)4, (-)-DET
4 Å MS
Reaction arrow head
CH2Cl2
-20 °C, 5 h
75 %
Product structure

This reaction is from the synthesis of Doliculide by Arun K. Ghosh. Show me the full synthesis.

Reactant structure
Ti(Oi-Pr)4, (-)-DET, t-BuOOH
4 Å MS
Reaction arrow head
CH2Cl2
-23 °C, 20.5 h
90 %
Product structure

This reaction is from the synthesis of Nupharamine by Isao Shimizu. Show me the full synthesis.

Reactant structure
t-BuOOH, Ti(Oi-Pr)4, (-)-DET
Reaction arrow head
CH2Cl2
-23 °C
92 %
Product structure
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